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Stochastic Gradient Descent (SGD) is a workhorse algorithm for continuous optimization. It is a folk belief among deep learning practitioners that learning rate decay in SGD substantially improves performance. However, it has remained unclear whether learning rate decay offers an asymptotic advantage for global nonconvex optimization. We answer this question in the affirmative by demonstrating a natural class of nonconvex functions for which, we prove that SGD with learning rate decay requires exponentially fewer gradient queries for global optimization than SGD with any fixed learning rate in the small-step size regime. To the best of our knowledge, this is the first exponential advantage that has been demonstrated for learning rate decay. The class of functions we consider includes many popular benchmark nonconvex functions. Our results provide a robust explanatory theory for the empirically observed benefits of learning rate decay for global optimization. We show that annealing performs the non-logconcave sampling task associated to the optimization problem in polynomial time, via a novel application of weak Poincaré inequalities.